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      2-溴-4-(三氟甲基)苯磺酰氯結構式

      中文名稱:2-溴-4-(三氟甲基)苯磺酰氯
      英文名稱:2-Bromo-4-(trifluoromethyl)benzene-1-sulfonyl chloride
      CAS:54403-98-4
      分子式: C7H3O2F3SClBr
      分子量:323.51472

      2-溴-4-(三氟甲基)苯磺酰氯 MSDS
      基礎信息
      國標編號:
      CAS:
      中文名稱: 2-溴-4-(三氟甲基)苯磺酰氯
      英文名稱: 2-Bromo-4-(trifluoromethyl)benzene-1-sulfonyl chloride
      別 名:
      分子式: C7H3O2F3SClBr
      分子量: 323.51472
      熔 點:
      密 度:
      蒸汽壓:
      溶解性:
      穩定性:
      外觀與性狀:
      危險標記: colspan="3"
      用 途:

      Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
          Product name        : 2-Bromo-4-(trifluoromethyl)benzenesulfonyl chloride    

      Section 2. HAZARDS IDENTIFICATION
        Classification of the substance or mixture
          According to Regulation (EC) No1272/2008
          Flammable liquids (Category 3)
          Skin corrosion (Category 1B)
          According to European Directive 67/548/EEC as amended.
          Flammable. Causes burns.
        Label elements
          Pictogram
          Signal word        Danger    
          Hazard statement(s)
          H226        Flammable liquid and vapour.    
          H314        Causes severe skin burns and eye damage.    
          Precautionary statement(s)
          P280        Wear protective gloves/ protective clothing/ eye protection/ face protection.    
          P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
          contact lenses, if present and easy to do. Continue rinsing.
          P310        Immediately call a POISON CENTER or doctor/ physician.    
          Hazard symbol(s)
          C        Corrosive    
          R-phrase(s)
          R10        Flammable.    
          R34        Causes burns.    
          S-phrase(s)
          S26        In case of contact with eyes, rinse immediately with plenty of water and    
          seek medical advice.
          S27        Take off immediately all contaminated clothing.    
          S36/37/39        Wear suitable protective clothing, gloves and eye/face protection.    
          S45        In case of accident or if you feel unwell, seek medical advice immediately    
          (show the label where possible).
        Other hazards - none

      Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
          Formula        : C7H3BrClF3O2S    
          Molecular Weight        : 323,51 g/mol    
          CAS-No.        EC-No.        Index-No.        Classification        Concentration    
        2-Bromo-4-(trifluoromethyl)benzenesulfonyl chloride
          54403-98-4        -        - Flam. Liq. 3; Skin Corr. 1B;        -    
          H226, H314
          C, R10 - R34
          For the full text of the H-Statements mentioned in this Section, see Section 16.

      Section 4. FIRST AID MEASURES
        General advice
          Consult a physician. Show this safety data sheet to the doctor in attendance.
        If inhaled
          If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
        In case of skin contact
          Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a
          physician.
        In case of eye contact
          Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
        If swallowed
          Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.
          Consult a physician.

      Section 5. FIRE-FIGHTING MEASURES
        Suitable extinguishing media
          For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires,
          apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray;
          solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
        Special protective equipment for fire-fighters
          Wear self contained breathing apparatus for fire fighting if necessary.
        Further information
          Use water spray to cool unopened containers.

      Section 6. ACCIDENTAL RELEASE MEASURES
        Personal precautions
          Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
          Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
          explosive concentrations. Vapours can accumulate in low areas.
        Environmental precautions
          Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
        Methods and materials for containment and cleaning up
          Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place
          in container for disposal according to local regulations (see section 13).

      Section 7. HANDLING AND STORAGE
        Precautions for safe handling
          Avoid inhalation of vapour or mist.
          Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic
          charge.
        Conditions for safe storage
          Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
          resealed and kept upright to prevent leakage. Store in cool place.
          Store under inert gas. Moisture sensitive.

      Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
        Personal protective equipment
        Respiratory protection
          Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with
          multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to
          engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
          respirator. Use respirators and components tested and approved under appropriate government
          standards such as NIOSH (US) or CEN (EU).
        Hand protection
          Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
          touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves
          after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
          The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
          standard EN 374 derived from it.
        Eye protection
          Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and
          approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
        Skin and body protection
          Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of
          protective equipment must be selected according to the concentration and amount of the dangerous
          substance at the specific workplace.
        Hygiene measures
          Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
          the end of workday.

      Section 9. PHYSICAL AND CHEMICAL PROPERTIES
        Appearance
          Form        viscous    
          Colour        yellow    
        Safety data
          pH        no data available    
          Melting point        no data available    
          Boiling point        235 - 236 °C - lit.    
          Flash point        35 °C - closed cup    
          Ignition temperature        no data available    
          Lower explosion limit no data available
          Upper explosion limit no data available
          Density        1,865 g/cm3 at 25 °C    
          Water solubility        no data available    

      Section 10. STABILITY AND REACTIVITY
        Chemical stability
          Stable under recommended storage conditions.
        Conditions to avoid
          Heat, flames and sparks.
        Materials to avoid
          Strong oxidizing agents
        Hazardous decomposition products
          Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur oxides, Hydrogen
          fluoride, Borane/boron oxides

      Section 11. TOXICOLOGICAL INFORMATION
        Acute toxicity
          no data available
        Skin corrosion/irritation
          no data available
        Serious eye damage/eye irritation
          no data available
        Respiratory or skin sensitization
          no data available
        Germ cell mutagenicity
          no data available
        Carcinogenicity
          IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
          probable, possible or confirmed human carcinogen by IARC.
        Reproductive toxicity
          no data available
        Specific target organ toxicity - single exposure
          no data available
        Specific target organ toxicity - repeated exposure
          no data available
        Aspiration hazard
          no data available
        Potential health effects
        Inhalation        May be harmful if inhaled. Material is extremely destructive to the tissue of the    
          mucous membranes and upper respiratory tract.
        Ingestion
          May be harmful if swallowed. Causes burns.
        Skin        May be harmful if absorbed through skin. Causes skin burns.    
        Eyes
          Causes eye burns.
        Signs and Symptoms of Exposure
          Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
          skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
          pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
          Headache, Nausea
        Additional Information
          RTECS: Not available

      Section 12. ECOLOGICAL INFORMATION
        Toxicity
          no data available
        Persistence and degradability
          no data available
        Bioaccumulative potential
          no data available
        Mobility in soil
          no data available
        PBT and vPvB assessment
          no data available
        Other adverse effects
          no data available

      Section 13. DISPOSAL CONSIDERATIONS
        Product
          Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as
          this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.
          Contact a licensed professional waste disposal service to dispose of this material.
        Contaminated packaging
          Dispose of as unused product.

      Section 14. TRANSPORT INFORMATION
        ADR/RID
          UN-Number: 2920 Class: 8 (3)        Packing group: II    
          Proper shipping name: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (2-Bromo-4-
          (trifluoromethyl)benzenesulfonyl chloride)
        IMDG
          UN-Number: 2920 Class: 8 (3)        Packing group: II        EMS-No: F-E, S-C    
          Proper shipping name: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (2-Bromo-4-
          (trifluoromethyl)benzenesulfonyl chloride)
          Marine pollutant: No
        IATA
          UN-Number: 2920 Class: 8 (3)        Packing group: II    
          Proper shipping name: Corrosive liquid, flammable, n.o.s. (2-Bromo-4-(trifluoromethyl)benzenesulfonyl chloride)



      SECTION 15 - REGULATORY INFORMATION
      N/A


      SECTION 16 - ADDITIONAL INFORMATION
      N/A
      2-溴-4-(三氟甲基)苯磺酰氯

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