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      分子式: C9H6NBr

      6-溴異喹啉 MSDS
      中文名稱: 6-溴異喹啉
      英文名稱: 6-Bromoisoquinoline
      別 名:
      分子式: C9H6NBr
      分子量: 208.05464
      熔 點:
      密 度:
      危險標記: colspan="3"
      用 途:

      SECTION 1: Identification of the substance/mixture and of the company/undertaking
        Product identifiers
          Product name        : 6-Bromoisoquinoline monohydrate    
          REACH No.        : A registration number is not available for this substance as the substance    
          or its uses are exempted from registration, the annual tonnage does not
          require a registration or the registration is envisaged for a later
          registration deadline.
        Relevant identified uses of the substance or mixture and uses advised against
          Identified uses        : Laboratory chemicals, Manufacture of substances    

      SECTION 2: Hazards identification
        Classification of the substance or mixture
        Classification according to Regulation (EC) No 1272/2008
          Acute toxicity, Oral (Category 4), H302
          Eye irritation (Category 2), H319
          For the full text of the H-Statements mentioned in this Section, see Section 16.
        Classification according to EU Directives 67/548/EEC or 1999/45/EC
          Xn Harmful        R22, R36    
          For the full text of the R-phrases mentioned in this Section, see Section 16.
        Label elements
        Labelling according Regulation (EC) No 1272/2008
          Signal word        Warning    
          Hazard statement(s)
          H302        Harmful if swallowed.    
          H319        Causes serious eye irritation.    
          Precautionary statement(s)
          P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
          contact lenses, if present and easy to do. Continue rinsing.
          Supplemental Hazard        none    
        Other hazards - none

      SECTION 3: Composition/information on ingredients
          Formula        : C9H6BrN · H2O    
          Molecular Weight        : 226,07 g/mol    
        Hazardous ingredients according to Regulation (EC) No 1272/2008
          Component        Classification        Concentration    
          CAS-No.        34784-05-9        Acute Tox. 4; Eye Irrit. 2;        <= 100="">
          H302, H319
        Hazardous ingredients according to Directive 1999/45/EC
          Component        Classification        Concentration    
          CAS-No.        34784-05-9        Xn, R22 - R36        <= 100="">
          For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

      SECTION 4: First aid measures
        Description of first aid measures
        General advice
          Consult a physician. Show this safety data sheet to the doctor in attendance.
        If inhaled
          If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
        In case of skin contact
          Wash off with soap and plenty of water. Consult a physician.
        In case of eye contact
          Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
        If swallowed
          Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
        Most important symptoms and effects, both acute and delayed
          The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
          section 11
        Indication of any immediate medical attention and special treatment needed
          no data available

      SECTION 5: Firefighting measures
        Extinguishing media
        Suitable extinguishing media
          Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
        Special hazards arising from the substance or mixture
          Carbon oxides, nitrogen oxides (NOx), Hydrogen bromide gas
        Advice for firefighters
          Wear self contained breathing apparatus for fire fighting if necessary.
        Further information
          no data available

      SECTION 6: Accidental release measures
        Personal precautions, protective equipment and emergency procedures
          Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
          adequate ventilation. Avoid breathing dust.
          For personal protection see section 8.
        Environmental precautions
          Do not let product enter drains.
        Methods and materials for containment and cleaning up
          Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
          containers for disposal.
        Reference to other sections
          For disposal see section 13.

      SECTION 7: Handling and storage
        Precautions for safe handling
          Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
          Provide appropriate exhaust ventilation at places where dust is formed.
          For precautions see section 2.2.
        Conditions for safe storage, including any incompatibilities
          Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
        Specific end use(s)
          Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

      SECTION 8: Exposure controls/personal protection
        Control parameters
        Components with workplace control parameters
        Exposure controls
        Appropriate engineering controls
          Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
          at the end of workday.
        Personal protective equipment
        Eye/face protection
          Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
          and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
        Skin protection
          Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
          (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
          contaminated gloves after use in accordance with applicable laws and good laboratory practices.
          Wash and dry hands.
          The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
          the standard EN 374 derived from it.
          Full contact
          Material: Nitrile rubber
          Minimum layer thickness: 0,11 mm
          Break through time: 480 min
          Material tested:Dermatril? (KCL 740 / Z677272, Size M)
          Splash contact
          Material: Nitrile rubber
          Minimum layer thickness: 0,11 mm
          Break through time: 480 min
          Material tested:Dermatril? (KCL 740 / Z677272, Size M)
          data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300,     test method: EN374
          If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
          contact the supplier of the CE approved gloves. This recommendation is advisory only and must
          be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
          anticipated use by our customers. It should not be construed as offering an approval for any
          specific use scenario.
        Body Protection
          Complete suit protecting against chemicals, The type of protective equipment must be selected
          according to the concentration and amount of the dangerous substance at the specific workplace.
        Respiratory protection
          For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
          level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
          Use respirators and components tested and approved under appropriate government standards
          such as NIOSH (US) or CEN (EU).
        Control of environmental exposure
          Do not let product enter drains.

      SECTION 9: Physical and chemical properties
        Information on basic physical and chemical properties
          a) Appearance        Form: solid    
          b) Odour        no data available    
          c) Odour Threshold        no data available    
          d) pH        no data available    
          e) Melting point/freezing        Melting point/range: 52 - 57 °C    
          f) Initial boiling point and no data available
          boiling range
          g) Flash point        > 110 °C    
          h) Evapouration rate        no data available    
          i) Flammability (solid, gas) no data available
          j) Upper/lower        no data available    
          flammability or
          explosive limits
          k) Vapour pressure        no data available    
          l) Vapour density        no data available    
          m) Relative density        no data available    
          n) Water solubility        no data available    
          o) Partition coefficient: n- log Pow: 2,919
          p) Auto-ignition        no data available    
          q) Decomposition        no data available    
          r) Viscosity        no data available    
          s) Explosive properties        no data available    
          t) Oxidizing properties        no data available    
        Other safety information
          no data available

      SECTION 10: Stability and reactivity
          no data available
        Chemical stability
          Stable under recommended storage conditions.
        Possibility of hazardous reactions
          no data available
        Conditions to avoid
          no data available
        Incompatible materials
          Strong oxidizing agents
        Hazardous decomposition products
          Other decomposition products - no data available
          In the event of fire: see section 5

      SECTION 11: Toxicological information
        Information on toxicological effects
        Acute toxicity
          no data available
        Skin corrosion/irritation
          no data available
        Serious eye damage/eye irritation
          no data available
        Respiratory or skin sensitisation
          no data available
        Germ cell mutagenicity
          no data available
          IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
          probable, possible or confirmed human carcinogen by IARC.
        Reproductive toxicity
          no data available
        Specific target organ toxicity - single exposure
          no data available
        Specific target organ toxicity - repeated exposure
          no data available
        Aspiration hazard
          no data available
        Additional Information
          RTECS: Not available
          To the best of our knowledge, the chemical, physical, and toxicological properties have not been
          thoroughly investigated.

      SECTION 12: Ecological information
          no data available
        Persistence and degradability
          no data available
        Bioaccumulative potential
          no data available
        Mobility in soil
          no data available
        Results of PBT and vPvB assessment
          PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
        Other adverse effects
          no data available

      SECTION 13: Disposal considerations
        Waste treatment methods
          Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with
          an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.
        Contaminated packaging
          Dispose of as unused product.

      SECTION 14: Transport information
        UN number
          ADR/RID: -        IMDG: -        IATA: -    
        UN proper shipping name
          ADR/RID: Not dangerous goods
          IMDG: Not dangerous goods
          IATA:        Not dangerous goods    
        Transport hazard class(es)
          ADR/RID: -        IMDG: -        IATA: -    
        Packaging group
          ADR/RID: -        IMDG: -        IATA: -    
        Environmental hazards
          ADR/RID: no        IMDG Marine pollutant: no        IATA: no    
        Special precautions for user
          no data available


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