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      (S)-(-)-2,2-雙(二苯基膦基氨)-5,5',6,6',7,7',8,8'-1,1-二萘 MSDS
      中文名稱: (S)-(-)-2,2-雙(二苯基膦基氨)-5,5',6,6',7,7',8,8'-1,1-二萘
      英文名稱: (S)-(-)-2,2'-Bis(N-diphenylphosphinoamino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl
      別 名:
      分子式: C44H42N2P2
      分子量: 660.76528
      熔 點:
      密 度:
      危險標記: colspan="3"
      用 途:

      Section 1: Product Identification
         S-(-)-2,2'-Bis(N-diphenylphosphinoamino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl, min. 95%
         Chemical Name:
         CAS Registry Number:       229177-79-1    
         Formula:       C44H42N2P2    
         EINECS Number:       none    
         Chemical Family:       organophosphine ligand    
         Synonym:       CTH-(S)-BINAM    

      Section 2: Composition and Information on Ingredients
         Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
         Title compound       229177-79-1       100%       no data       no data    

      Section 3: Hazards Identification
         Emergency Overview:       Irritating to skin and eyes. May be irritating to the respiratory tract. May be harmful if swallowed    
         Primary Routes of Exposure:       Ingestion, skin, eyes    
         Eye Contact:       Causes mild to moderate irritation to the eyes.    
         Skin Contact:       Causes mild to moderate irritation of the skin.    
         Inhalation:       May be irritating to the nose, mucous membranes and respiratory tract.    
         Ingestion:       No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.    
         Acute Health Affects:       Irritating to skin and eyes. May be irritating to the respiratory tract.    
         Chronic Health Affects:       No information on long-term chronic effects.    
         NTP:       No    
         IARC:       No    
         OSHA:       No    

      SECTION 4: First Aid Measures
         Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
         Eye Exposure:
         assistance in keeping their eye lids open. Get immediate medical attention.
         Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
         Skin Exposure:
         irritation persists.
         Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
         in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
         Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
         vomiting only if directed by medical personnel.

      SECTION 5: Fire Fighting Measures
         Flash Point:       no data    
         Autoignition Temperature:       none    
         Explosion Limits:       none    
         Extinguishing Medium:       carbon dioxide, dry powder or foam.    
         If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
         Special Fire Fighting Procedures:
         self-contained breathing apparatus and full protective clothing.
         Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.    
         Decomposion Products:
         Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

      SECTION 6: Accidental Release Measures
         Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
         Spill and Leak Procedures:
         swept up.

      SECTION 7: Handling and Storage
         Handling and Storage:       Keep container tightly closed. Store in a cool, dry place.    

      SECTION 8: Exposure Controls and Personal Protection
         Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
         Skin Protection:       Wear protective clothing and gloves.    
         Ventilation:       Handle the material in an efficient fume hood.    
         If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
         Protection Program to be in compliance with 29 CFR 1910.134.
         Ventilation:       Handle the material in an efficient fume hood.    
         Additional Protection:       No additional protection required.    

      SECTION 9: Physical and Chemical Properties
         Color and Form:       white solid    
         Molecular Weight:       660.77    
         Melting Point:       no data    
         Boiling Point:       no data    
         Vapor Pressure:       no data    
         Specific Gravity:       no data    
         Odor:       none    
         Solubility in Water:       insoluble    

      SECTION 10: Stability and Reactivity
         Stability:       air and moisture stable    
         Hazardous Polymerization:       no hazardous polymerization    
         Conditions to Avoid:       none    
         Incompatibility:       oxidizing agents and halogens    
         Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.    

      SECTION 11: Toxicological Information
         RTECS Data:       No information available in the RTECS files.    
         Carcinogenic Effects:       no data    
         Mutagenic Effects:       no data    
         Tetratogenic Effects:       no data    

      SECTION 12: Ecological Information
         Ecological Information:       No information available    

      SECTION 13: Disposal Considerations
         Disposal:       Dispose of according to federal, state, and local regulations.    

      SECTION 14: Transportation
         Shipping Name (CFR):       Non-hazardous    
         Hazard Class (CFR):       NA    
         Additional Hazard Class (CFR):       NA    
         Packaging Group (CFR):       NA    
         UN ID Number (CFR):       NA    
         Shipping Name (IATA):       Non-hazardous    
         Hazard Class (IATA):       NA    
         Additional Hazard Class (IATA):       NA    
         Packaging Group (IATA):       NA    
         UN ID Number (IATA):       NA    

      SECTION 15: Regulatory Information
         TSCA:       Not listed in the TSCA inventory.    
         SARA (Title 313):       Title compound not listed.    
         Second Ingredient:       none    



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